17

Cyclometallation on platinum(ii) complexes; the role of the solvent and added base donor capability on the reaction mechanismsElectronic supplementary information (ESI) available: Listings of selected bond lengths (?) and angles (�) for complex 2 with estimated standard deviations, crystallographic and refinement data for complex 2 and listing of observed rate constants for the cyclometallation reaction of complex 1. Plot of the molecular structure of complex 2 and that of the observed rate constants corresponding to the first reaction step determined when proton sponge or neat solvent were used. 1H NMR spectra of the mixture of Z and E isomers of complex 1. See http://www.rsc.org/suppdata/dt/b3/b306243k/

Crespo, Margarita, Font-Bardia, Merc�, Granell, Jaume, Mart�nez, Manuel, Solans, Xavier
Journal:
Dalton Transactions
Année:
2003
Langue:
english
Fichier:
PDF, 183 KB
english, 2003
47

ChemInform Abstract: Ismine.

F. VILADOMAT, C. CODINA, J. BASTIDA, X. SOLANS, M. FONT-BARDIA
Journal:
ChemInform
Année:
1998
Fichier:
PDF, 23 KB
1998